US 12453952 B1Patent grantUnited States

Manganese-Borate Composite for Pollutant Removal

Official patent title

Nanocomposite for the immobilization or degradation of pollutants

Arabic title: مركب نانوي لتثبيت الملوثات أو تحللها

Invention

Invention

Problem

Treating water containing both inorganic contaminants and persistent organics may require separate process steps. A multifunctional solid must demonstrate activity, stability, recovery, and safety in representative water.

Why it matters

One material capable of immobilization and light-assisted degradation could simplify remediation systems and broaden the treatment range for industrial or municipal effluents.

Approach

The disclosed particulate composite combines carbon with calcium diborate, manganese-magnesium borate, and calcium borate phases and is claimed for direct inorganic-contaminant immobilization and irradiated organic-pollutant degradation.

Who may benefit

Potential beneficiaries include environmental-remediation companies, wastewater laboratories, photocatalyst developers, industrial-water operators, and suppliers of advanced treatment media.

Potential value

The material provides a defined manganese-containing multiphase borate composition, 65–75 nm crystallite size, 100–200 nm median particle size, and two claimed pollutant-treatment modes.

Background

Background

Inorganic ions and organic micropollutants behave differently in water, often requiring adsorption, precipitation, oxidation, or biological treatment in sequence. Multiphase solids may combine binding sites with light-responsive redox activity. To prove utility, however, experiments must quantify contaminant removal, adsorption capacity, transformation kinetics, mineralization, intermediate products, and material leaching. Reuse and separation also influence process cost. The disclosure presents a calcium-, manganese-, magnesium-, boron-, and carbon-containing composite as a candidate for both immobilization and irradiated degradation.

Technology overview

Technology overview

XRD identifies orthorhombic CaB2O4, triclinic MnMgB2O5, and Ca3B2O6, while elemental ranges cover C, Ca, B, Mn, and Mg. The composite has a claimed 65–75 nm average crystallite size, substantially spherical particles and agglomerates, and 100–200 nm Dv50 by HRTEM. Metal salts and boric acid are chelated in water, combined with a polyol to form a gel, dried at 150–300 °C, and calcined at 600–800 °C. Claims cover aqueous immobilization and degradation under actinic light.

Potential applications

Potential applications

  1. Inorganic-contaminant immobilization.
  2. Photochemical organic-pollutant degradation.
  3. Wastewater treatment-media research.
  4. Manganese-borate nanocomposite development.

Evidence-supported advantages

Evidence-supported advantages

  1. Targets two pollutant classes.
  2. Combines three crystalline borate phases.
  3. Defines elemental, crystallite, and particle-size ranges.
  4. Uses spherical particles and aggregates.
  5. Provides a solution-gel preparation route.

Development stage

Development stage

Laboratory synthesis and phase, elemental, and particle characterization are described, with claimed water-treatment methods; contaminant capacity, degradation kinetics, by-products, leaching, and reuse were not established. The development stage was not independently verified.

Commercial opportunity

Commercial opportunity

The composite could be screened for mixed wastewater and remediation systems. Development needs contaminant-specific adsorption and degradation tests, mineralization and by-product analysis, light-energy demand, leaching and ecotoxicity, magnetic or filtration recovery options, repeat-use cycles, competing-solute and real-effluent validation, reactor scale-up, calcination economics, and environmental regulatory review.

Patent classifications

Patent classifications

WIPO IPC

  • B01J20/04Chemical or physical processes, e.g. catalysis or colloid chemistry; their relevant apparatus
  • B01J20/28Chemical or physical processes, e.g. catalysis or colloid chemistry; their relevant apparatus
  • C02F101/10Treatment of water, wastewater, sewage or sludge

CPC

  • B01J20/041Chemical or physical processes, e.g. catalysis or colloid chemistry; their relevant apparatus
  • B01J20/28004Chemical or physical processes, e.g. catalysis or colloid chemistry; their relevant apparatus
  • B01J35/39Chemical or physical processes, e.g. catalysis or colloid chemistry; their relevant apparatus
  • B01J35/70Chemical or physical processes, e.g. catalysis or colloid chemistry; their relevant apparatus
  • B01J20/28019Chemical or physical processes, e.g. catalysis or colloid chemistry; their relevant apparatus
  • C02F1/725Treatment of water, wastewater, sewage or sludge
  • C02F1/30Treatment of water, wastewater, sewage or sludge
  • B01J20/28011Chemical or physical processes, e.g. catalysis or colloid chemistry; their relevant apparatus
  • B01J20/3078Chemical or physical processes, e.g. catalysis or colloid chemistry; their relevant apparatus
  • C02F1/288Treatment of water, wastewater, sewage or sludge
  • C01B35/128Non-metallic elements; compounds thereof
  • C02F1/281Treatment of water, wastewater, sewage or sludge
  • C02F2101/30Treatment of water, wastewater, sewage or sludge
  • C02F2305/10Treatment of water, wastewater, sewage or sludge
  • C02F2305/08Treatment of water, wastewater, sewage or sludge
  • C02F2101/10Treatment of water, wastewater, sewage or sludge
  • C02F1/283Treatment of water, wastewater, sewage or sludge

Inventors

Inventors

  • First inventorEhab Abdelhamed Abdelrahman Ahmed
  • InventorMortaga Mohamed Mostafa Abou-Krisha
  • InventorAbdulrahman Ghonaim Awad Alhamzani

Keywords

Keywords

  • pollutant immobilization
  • photodegradation
  • calcium borate
  • manganese magnesium borate
  • water treatment
  • nanocomposite
  • actinic irradiation

Patent document and drawings

Patent document and drawings

The patent publication is mapped to this record. Patent drawings remain within that publication; no separately cleared public media package has been supplied.