US 12147153 B1Patent grantUnited States

Nanocellulose X-Ray Imaging Film

Official patent title

Nanocellulose X-ray film and method of making

Arabic title: غشاء أشعة سينية من السليلوز النانوي وطريقة تصنيعه

Invention

Invention

Problem

Conventional radiographic film commonly relies on petroleum-derived base materials, creating environmental concerns while still requiring long-term stability, moisture resistance, and sufficient mechanical strength for handling.

Why it matters

Film-based radiography remains in use, including in dental settings, despite the spread of digital imaging. A partially bio-derived film could reduce reliance on petroleum-based inputs if imaging and handling requirements are met.

Approach

The film combines acid-hydrolyzed palm mesocarp, starch, cellulose and nanocellulose, a synthetic polymer, plant hydrogels, cyanoacrylate adhesive, glycerin, and a Jamun-derived X-ray-sensitive dye. The method blends, pressure-heats, acid-treats, compounds, cures, and dries the mixture under specified conditions.

Who may benefit

Potential beneficiaries include radiographic-film and dental-imaging suppliers, specialty-film manufacturers, biomaterials researchers, and palm-processing organizations seeking higher-value uses for plant material.

Potential value

The disclosure offers a defined route to an X-ray-sensitive film with substantial plant-derived content and claimed mechanical, low-water-absorption, carbonate, and crack-resistance properties, while retaining a synthetic-polymer component.

Background

Background

Medical and dental facilities continue to use conventional X-ray film for some examinations. Such films typically rely on a petroleum-derived polyester base that supports the photosensitive layer during processing, storage, and handling. Replacing part of that structure with biological feedstocks requires more than simply using plant matter: the finished film must remain dimensionally stable, resist heat and moisture, and avoid tearing or cracking. The patent addresses this combination of environmental and material-performance needs through palm-derived nanocellulose, plant hydrogels, and a plant-derived sensitive dye.

Technology overview

Technology overview

Palm mesocarp is blended with water, heated, and hydrolyzed with an inorganic acid to generate a nanocellulose-containing mixture. Starch, cellulose, polyvinyl chloride in some embodiments, aloe-vera/okra/Acacia hydrogels, cyanoacrylate, glycerin, and Jamun dye are added before curing at 125–175 °C and drying at 60–100 °C. The claimed film contains 32.5–45 wt.% cellulose and specified ranges for tensile, water-absorption, carbonate, and crack-test properties.

Potential applications

Potential applications

  1. Bio-derived substrates for conventional radiographic-film development.
  2. Potential dental X-ray film products after imaging validation.
  3. Specialty photosensitive films using plant-derived dye and cellulose.
  4. Value-added material pathways for palm mesocarp feedstock.

Evidence-supported advantages

Evidence-supported advantages

  1. Uses palm mesocarp and a Jamun-derived dye as plant-based inputs.
  2. Provides a detailed formulation and staged thermal preparation method.
  3. Incorporates nanocellulose with a claimed 10–35 nm particle size.
  4. Reports tensile, water-absorption, carbonate, and crack-test property ranges.

Development stage

Development stage

Film preparation and mechanical, water-absorption, and crack-testing properties are described; commercialization was not established.

Commercial opportunity

Commercial opportunity

The formulation may interest specialty-film, dental-imaging, and biomaterials manufacturers exploring lower-petroleum product lines. Before product development, the X-ray sensitivity, image quality, processing compatibility, shelf life, and regulatory requirements would need direct validation. Compatibility with existing film processors would also need assessment.

Patent classifications

Patent classifications

WIPO IPC

  • G03C1/73Photosensitive materials for photography; photographic processes, e.g. cine, X-ray, colour or stereophotography; auxiliary photographic processes
  • G03C1/76Photosensitive materials for photography; photographic processes, e.g. cine, X-ray, colour or stereophotography; auxiliary photographic processes

CPC

  • G03C1/76Photosensitive materials for photography; photographic processes, e.g. cine, X-ray, colour or stereophotography; auxiliary photographic processes
  • G03C1/73Photosensitive materials for photography; photographic processes, e.g. cine, X-ray, colour or stereophotography; auxiliary photographic processes
  • G03C1/795Photosensitive materials for photography; photographic processes, e.g. cine, X-ray, colour or stereophotography; auxiliary photographic processes
  • G03C1/731Photosensitive materials for photography; photographic processes, e.g. cine, X-ray, colour or stereophotography; auxiliary photographic processes

Inventors

Inventors

  • First inventorABM Sharif Hossain
  • InventorMohammed Saad Aleissa
  • InventorHassan Ahmed Rudayni
  • InventorSalem Ali S. Alyami
  • InventorMohammed Musa Zahrany
  • InventorNasir A. Ibrahim

Keywords

Keywords

  • nanocellulose
  • X-ray film
  • palm mesocarp
  • Jamun dye
  • plant hydrogel
  • radiography
  • bio-derived film
  • mechanical properties

Patent document and drawings

Patent document and drawings

The patent publication is mapped to this record. Patent drawings remain within that publication; no separately cleared public media package has been supplied.